Ajai K Singh




Ajai K Singh



Professor


Born: Aligarh, Uttar Pradesh
Ph. D. (Prof. R. P. Singh), University of Delhi, 1977
Indian Institute of Technology, Delhi, 1982-present
Research Associate (Prof. W. R. McWhinnie’s group), University of Aston, Birmingham, U. K.
Coordinator, "Modern Trends in Inorganic Chemistry XI", December 2005
Visiting Professor at Pohang University of Science and Technology, South Korea, Oct. 2007.
Professor (HAG): 2009
Head, Department of Chemistry, 2009-2012
Honorary member (external) of Science Faculty, University of Delhi (2002-2005; 2008-2011).
Co-Chair, 3rd Asian conference on Coordination Chemistry, Oct 2011
President Inorganic Section, Indian Council of Chemists 2011
Member Senate IIT Indore; 2011
Associate Editor, RSC Advances 2015-
Fellow of the Royal Society of Chemistry (FRSC)


Group Webpage



Research Interests


Broadly research interest is "Coordination and Organometallic Chemistry” with focus on Catalyst Designing Particularly using Organochalcogen Ligands for coupling Reactions, Oxidation and Transfer Hydrogenation etc; Metal Chalcogenide Nano-particles: Single source precursors, Catalytic Applications.


research pic
Graphene oxide based catalyst

Selected Publications


  1. Palladacycles of unsymmetrical (N,C‾,E) (E = S/Se) pincers based on indole: their synthesis, structure and applications in the catalysis of Heck coupling and allylation of aldehydes, M. P. Singh, F. Saleem, G. K. Rao, S. Kumar, H. Joshi and A. K Singh, Dalton Trans., 2016, 45, 6718.
  2. Acridine based (S,N,S) pincer ligand: designing of silver(I) complexes for efficient activation of A3(aldehyde, alkyne and amine) coupling, O. Prakash, H. Joshi, U. Kumar, A. K. Sharma and A. K. Singh, Dalton Trans., 2015, 44, 1962.
  3. Tetragonal Cu2Se nanoflakes: synthesis using selenated propylamine as Se source and activation of Suzuki and Sonogashira cross coupling reactions, V. V. Singh and A. K. Singh, Dalton Trans., 2015, 44, 725.
  4. 2-Propanol vs glycerol as hydrogen source in catalytic activation of transfer hydrogenation with (eta6-benzene)ruthenium(II) complexes of unsymmetrical bidentate chalcogen ligands, A. K. Sharma, H. Joshi, K. N. Sharma, P. L. Gupta and A. K. Singh Organometallics, 2014, 33, 3629.
  5. Formation and role of palladium chalcogenide and other species in Suzuki-Miyaura and Heck C-C coupling reactions catalyzed with palladium(II) complexes of organochalcogen ligands: realities and speculations, A. Kumar, G. K. Rao, S. Kumar and A. K. Singh, Organometallics, 2014, 33, 2921.



Group

      Group Members


  • Dr. Ved Vati Singh
  • Dr. Poornima Singh
  • Dr. Fariha Saleem
  • Satyendra Kumar (Ph D)
  • Alpesh Kumar Sharma (Ph D)
  • Pooja Dubey (Ph D)
  • Renu Bhaskar (Ph D)
  • Sonu (Ph D)